{"id":282,"date":"2014-02-25T10:24:52","date_gmt":"2014-02-25T10:24:52","guid":{"rendered":"http:\/\/grupodeespectroscopia.es\/mw\/?p=282"},"modified":"2018-12-24T14:53:31","modified_gmt":"2018-12-24T14:53:31","slug":"sevoflurane%c2%b7%c2%b7%c2%b7benzene-published-in-angewandte","status":"publish","type":"post","link":"https:\/\/grupodeespectroscopia.es\/MW\/sevoflurane%c2%b7%c2%b7%c2%b7benzene-published-in-angewandte\/","title":{"rendered":"Sevoflurane\u00b7\u00b7\u00b7benzene published in Angewandte"},"content":{"rendered":"<p>A work in collaboration with the <a href=\"http:\/\/faculty.virginia.edu\/bpate-lab\/\" target=\"_blank\">Pate group<\/a> in Virginia examined the weakly-bound cluster of sevoflurane\u00b7\u00b7\u00b7benzene ans was published in <a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201309848\/abstract\" target=\"_blank\">Angewandte Chemie<\/a>. The primary interaction is a relatively strong C-H\u00b7\u00b7\u00b7pi hydrogen bond. The presence of additional C-H\u00b7\u00b7\u00b7F weak interactions hinders the six-fold symmetric internal rotation of benzene around sevoflurane. This is probably the first time that such a V6 barrier has been determined in a intermolecular complex.<\/p>\n<p><a href=\"http:\/\/grupodeespectroscopia.es\/mw\/wp-content\/uploads\/2014\/10\/sevo-benzene.gif\"><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter wp-image-283\" src=\"http:\/\/grupodeespectroscopia.es\/mw\/wp-content\/uploads\/2014\/10\/sevo-benzene.gif\" alt=\"sevo-benzene\" width=\"264\" height=\"255\" \/><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>A work in collaboration with the Pate group in Virginia examined the weakly-bound cluster of sevoflurane\u00b7\u00b7\u00b7benzene ans was published in Angewandte Chemie. The primary interaction is a relatively strong C-H\u00b7\u00b7\u00b7pi hydrogen bond. The presence of additional C-H\u00b7\u00b7\u00b7F weak interactions hinders the six-fold symmetric internal rotation of benzene around sevoflurane. This is probably the first time &hellip;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[22],"tags":[],"acf":[],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/posts\/282"}],"collection":[{"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/comments?post=282"}],"version-history":[{"count":1,"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/posts\/282\/revisions"}],"predecessor-version":[{"id":284,"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/posts\/282\/revisions\/284"}],"wp:attachment":[{"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/media?parent=282"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/categories?post=282"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/grupodeespectroscopia.es\/MW\/wp-json\/wp\/v2\/tags?post=282"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}